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September 22, 2025

Unlocking uranium’s hidden influence in the behavior of plutonium alloys

Work advances understanding of nuclear materials performance

Scientists hypothesized where uranium would appear in the zeta phase of a uranium-plutonium alloy. Uranium atoms are blue and plutonium atoms are yellow. Credit to: Sarah Hernandez, Franz Freibert, Journal of Vacuum Science & Technology A, CC BY-NC 4.0

Drawing on Los Alamos’s decades-long leadership in actinide science, Laboratory research has revealed how uranium impurities affect the structure of plutonium alloys by forming strong, short bonds that are stable in plutonium-gallium materials at the atomic level.   

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Why this matters: Scientists now have a better understanding of how plutonium alloys behave under radiation damage and stress due to the radioactive decay uranium daughter product from plutonium-239. This insight offers valuable guidance for improving and predicting the performance of plutonium alloys in advanced nuclear applications. 

More about the work:

  • Through first-principles calculations and analysis of existing experimental data, this work provides a comprehensive understanding of the bonding and electronic structure of uranium in delta plutonium-gallium alloys and provides further insights into the relatively unknown uranium-plutonium zeta-phase binary alloy.
  • The work was published in a special collection of Journal of Vacuum Science & Technology, honoring Wilhelm Wolfer (Lawrence Livermore National Laboratory), an influential contributor to actinide science and plutonium aging. The paper’s co-author, Franz Friebert, served as a guest editor.

Funding: This work was supported by the Laboratory Directed Research and Development program at Los Alamos and the National Nuclear Security Administration’s Stockpile Research, Technology, and Engineering program.

LA-UR-25-29137

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