Like other rare-earth elements, discovering ytterbium was a long process!
Ytterbium’s story goes back to 1789, when Swedish chemist Johan Gadolin discovered the element yttrium (not to be confused with ytterbium) in an ore sample from the town of Ytterby, Sweden. It turned out, though, that the sample of yttrium oxide that Gadolin had extracted wasn’t pure. In 1843, Swedish chemist Carl Gustaf Mosander found the new elements terbium and erbium in yttrium oxide as well. But these elements weren’t in their pure form, either.
It wasn’t until 1878 that Swiss chemist Jean Charles Galissard de Marignac found ytterbium, a new element, in a sample of erbium. The rare-earth elements are so similar that it was hard to separate out the ytterbium, but after a lot of hard work, de Marignac succeeded. Sometimes, persistence pays off!
As it happens, at around the same time that de Marignac found ytterbium, so too did Austrian chemist Carl Auer von Welsbach. Von Welsbach named the new element aldebaranium, but it was de Marignac who wound up getting credit for finding the element, and de Marignac’s name for the element—ytterbium, after the Swedish town—is the one that stuck.
Incidentally, in 1907, French chemist Georges Urbain succeeded in splitting the ytterbium that de Marignac had discovered into two elements: ytterbium and a new element that he called lutetium.
