Radium was discovered by physicist Marie Curie and her husband Pierre Curie. They found it in a large sample of uraninite, a radioactive mineral ore rich in uranium. This was incredibly difficult work because there is so little radium in uranite—only about one gram of radium in seven tons of uranite. After removing all the uranium and then a few other elements, the remaining material was still radioactive! This made the Curies curious and they suspected that they had found something new.
The Curies tried flame spectroscopy to identify what they had found, measuring the exact colors present in a flame when they burned the material. Each element has a unique color signature, but the specific deep-red shades that they saw when they tested their mystery material didn’t match any known element.
In 1898, the Curies reported their discovery of a compound containing a new element and named it radium for the intense radioactive rays it emits. Their samples produced a faint blue glow that could be seen in the dark because of the radioactivity affecting the surrounding air!
In 1911, Marie Curie and French chemist André-Louis Debierne isolated pure radium metal, using electrolysis (using an electrical current to drive the chemical separation), by splitting apart radium chloride. The process also required mixing the radium with mercury and then boiling off the mercury.
