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Praseodymium

59
140.9
Pr
Praseodymium

Element Stats

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Physical

Physical Properties
PropertyValuePropertyValue
AppearanceSoft, silvery-gray metal
ClassificationLanthanidesDensity6.773 g/cm³ at STP
Boiling Point3403 KMelting Point1204 K

Atomic

Atomic Properties
PropertyValuePropertyValue
Atomic Number59Atomic Mass140.90767
Van Der Waals Radius239Atomic Radius (empirical)182

Electronic & Chemical

Electronic and Chemical Properties
PropertyValuePropertyValue
Electronegativity1.13Electron Affinity93 kJ/mol
Electron Configuration1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f3
Oxidation States5, 4, 3, 2
Ionization Energies

Showing all 5 ionization energies.

  1. 527 kJ/mol
  2. 1020 kJ/mol
  3. 2086 kJ/mol
  4. 3761 kJ/mol
  5. 5551 kJ/mol

History

Praseodymium is one of those elements that just can’t stand to be alone. That’s why you’ll only ever find praseodymium in nature alongside other rare earth metals, such as cerium, lanthanum, or praseodymium’s sister element, neodymium. In fact, praseodymium and neodymium are so similar that for decades, scientists couldn’t tell them apart!

In 1841, Swedish chemist Carl Mosander found what he thought to be two new elements in a sample of the mineral cerite. He called these two supposed elements “lanthanum” and “didymium.” However, in 1885, Austrian chemist Carl Auer von Welsbach succeeded in splitting didymium up into two elements.

Von Welsbach was a student of German chemist Robert Bunsen, who, in addition to inventing the Bunsen burner, helped develop the technique of spectroscopy (which involves burning a substance and examining the light emitted in the process to determine what the substance was made of). Using spectroscopy, von Welsbach was able to prove that the two elements he’d separated out from didymium were indeed distinct. He named the elements neodidymium (meaning “new didymium”) and praseodidymium (meaning “green didymium,” after the element’s oxide’s color). The name “praseodidymium” was then modified to “praseodymium,” which is what we call the element today.

Properties

Like other rare earth metals, praseodymium looks like silver. Praseodymium is moderately soft, ductile (meaning it can be stretched without breaking), and malleable (meaning that it can be hammered or shaped without breaking). Because rare-earth metals share many similar properties, praseodymium can often be substituted seamlessly in most applications involving rare-earth metals.

Praseodymium is reactive enough that it needs to be stored in mineral oil or sealed in plastic, or else it will form a greenish layer of oxide.

Uses

Praseodymium can be used in a ceramic glaze called Praseodymium Yellow, which is remarkably bright in color—think of banana-flavored Laffy Taffy! Praseodymium can also be mixed into zirconia to give inexpensive jewelry a greenish tint.

Praseodymium is used in praseodymium-neodymium magnets, which are in everything from electric or hybrid cars and wind turbines to computer hard drives, cell phones, and more. Alloyed with magnesium, praseodymium can help create very strong metals that are used in things like aircraft engines. Mixed with its sister element neodymium, praseodymium is often used in glasses designed to protect the eyes of welders or craftspeople, or of people in tanning beds.

Compounds

Praseodymium-nickel metals can be used in magnetic refrigeration. In fact, these magnets have been used by scientists to approach absolute zero—the coldest temperature imaginable!

Other praseodymium compounds, such as praseodymium(III) oxalate, are used to give ceramics, glass, and other substances a yellow color. Mixed with other elements, praseodymium oxide can help catalyze oxidation (when an element loses electrons during a chemical reaction).

Forms

Praseodymium only has one naturally occurring isotope, praseodymium-141, which is stable (non-radioactive). Scientists have produced around 40 praseodymium radioisotopes. Praseodymium-143 has a half-life of nearly 14 days, while all the other isotopes have half-lives of less than one day, and most have half-lives of less than one minute.

Sources

Like other rare earth metals, most praseodymium comes from monazite and bastnäsite ores. China is the top producer of these ores, so it’s the top producer of praseodymium, too. Russia and Malaysia also produce praseodymium. Praseodymium also occurs as a product of fissioning uranium. 

Fun Facts

What's in a name?

Praseodymium has the most syllables of all the element names.

Say atomic cheese!

A team of physicists led by Zhen Chen achieved atomic resolution by capturing the atoms of praseodymium orthoscandate with electron ptychography. The team proved it’s possible to get a crystal-clear image of an atom, the highest image resolution possible!

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