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Iridium

77
192.2
Ir
Iridium

Element Stats

Select a temperature unit to update boiling and melting point values.

Physical

Physical Properties
PropertyValuePropertyValue
AppearanceHard, dense, silvery-white metal
ClassificationTransition MetalsDensity22.56 g/cm³ at STP
Boiling Point4403 KMelting Point2719 K

Atomic

Atomic Properties
PropertyValuePropertyValue
Atomic Number77Atomic Mass192.2173
Van Der Waals Radius202Atomic Radius (empirical)136

Electronic & Chemical

Electronic and Chemical Properties
PropertyValuePropertyValue
Electronegativity2.2Electron Affinity150.94 kJ/mol
Electron Configuration1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d7
Oxidation States-3, -1, 0, 1, 2, 3, 4, 5, 6, 7, 8, 9
Ionization Energies

Showing all 2 ionization energies.

  1. 880 kJ/mol
  2. 1600 kJ/mol

History

Smithson Tennant, an English chemist, discovered iridium in 1803 in the residue of crude platinum, after dissolving it in aqua regia, a mixture of nitric and hydrochloric acids. Because of the bright colors of iridium’s salts, Tennant named the element after the Greek goddess Iris—who was known for leaving behind a rainbow.

Much like its supernatural namesake, iridium does not appear naturally on the Earth’s surface. Iridium has extraterrestrial origins and only a very thin layer of iridium exists in the Earth's crust. The iridium on earth was likely caused by a large meteor or asteroid hitting the Earth, because meteors and asteroids contain such high levels of iridium.

Properties

Iridium is white and looks like platinum but has a slight yellow tinge. Because of its brittleness, hardness, and high melting point, solid iridium is difficult to shape and mold, so it's often used in its powder form instead.

If elements had personalities, iridium would be the queen of chill. Iridium is unbothered by acids (including aqua regia), unchanged by air, and unconcerned with water (it's the most corrosion-resistant metal!).

But when there’s oxygen around and at high temperatures, iridium does react with cyanide salts, halogens, and oxygen itself. Iridium also reacts directly with sulfur (at atmospheric pressure) and creates iridium disulfide.

Uses

Iridium is used for coating optical lenses to reduce glare and improve clarity in certain lighting conditions. It also helps reduce the amount of scratching that might appear on camera and telescope lenses. But don’t get this element in your eyes: it can cause irritation!

Compounds

Important compounds of iridium are chlorides and iodides that are used as industrial catalysts. Catalysts help speed up chemical reactions, but unlike other chemicals in the reaction, a catalyst is not used up.

Forms

Iridium is mostly used in alloys. Osmium-iridium alloys are used for fountain pen nibs and for compass bearings. Iridium appears in solid form, also, but it is very brittle and difficult to work with.

Sources

Iridium is mostly found in igneous deposits (volcanic) and asteroid impact craters. The largest known iridium reserves are located in South Africa (near the largest known asteroid impact site, the Vredefort impact structure). There are other deposits in large copper–nickel deposits in Russia and an asteroid impact crater in Canada. Smaller reserves are found in the United States.

Iridium is also found in small deposits with platinum in alluvial (running water) deposits.

Fun Facts

A discovery 65 million years in the making

If no one was around to see it, why do we think an asteroid killed the dinosaurs? Iridium! The layer of sediment marking the end of the dinosaur era contains abnormally high levels of the colorful element. Because iridium is way more abundant in meteorites than the rest of the Earth’s crust, scientists think an iridium-rich asteroid struck the Earth, spreading the element and causing dinosaur extinction in the aftermath of its impact.

Avengers assemble

In Marvel’s Avengers, Loki needs iridium to stabilize the Tesseract Accelerator portal to bring the Chitauri to Earth and begin the Battle of New York. Iron Man saves the day and New York City by taking a nuclear missile through the iridium-stabilized portal to destroy the Chitauri Command Center and disable their forces on Earth.

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