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Gallium

31
69.72
Ga
Gallium

Element Stats

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Physical

Physical Properties
PropertyValuePropertyValue
AppearanceSoft, silvery-white metal
ClassificationPost-Transition MetalsDensity5.907 g/cm³ at STP
Boiling Point2676 KMelting Point302.9146 K

Atomic

Atomic Properties
PropertyValuePropertyValue
Atomic Number31Atomic Mass69.7231
Van Der Waals Radius187Atomic Radius (empirical)135

Electronic & Chemical

Electronic and Chemical Properties
PropertyValuePropertyValue
Electronegativity1.81Electron Affinity28.9 kJ/mol
Electron Configuration1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p1
Oxidation States3, 2, 1, -1, -2, -4, -5
Ionization Energies

Showing all 4 ionization energies.

  1. 578.8 kJ/mol
  2. 1979.3 kJ/mol
  3. 2963 kJ/mol
  4. 6180 kJ/mol

History

In 1871, Dmitri Mendeleev, creator of the periodic table, predicted the existence of element 31 based on trends in his table. Based on its position within the table (between the known elements aluminum and indium), he named the undiscovered element eka-aluminum and correctly deduced many of its properties, including its density and low melting point—all before the physical element was actually discovered!

Gallium was discovered not long after, in 1875, by chemist Paul-Émile Lecoq de Boisbaudran. He identified the element within a sample of the zinc ore sphalerite by observing its two violet lines on a spectrometer—a device that uses light diffraction to show the unique “color fingerprint” of each element. In the same year, de Boisbaudran obtained a sample of the free metal by chemically separating it from hydroxide. His name for the element comes from the Latin word Gallia, meaning Gaul, a region that once encompassed his homeland of France.

Gallium’s discovery was a landmark confirmation that the periodic table was more than just a way to classify the elements—it was a predictive scientific model. Mendeleev’s table showed that the elemental properties followed periodic trends, even for the elements we hadn’t yet discovered.

Properties

Elemental gallium has a beautiful, silvery appearance. The metal expands by 3.1 percent when it solidifies and fractures conchoidally, similar to how glass breaks in an unpredictable pattern.  

Gallium is one of four metals—the others being mercury, cesium, and rubidium—that is liquid near room temperature. It melts in a person’s hands at the normal body temperature of 98.6 °F. Gallium’s liquid range is among the widest of all metals, and it has a low vapor pressure even at high temperatures. 

Uses

Gallium readily alloys (or combines) with most metals and since its discovery has been widely used in alloys that require low melting points. For example, gallium alloys are used in thermometers as a safe and environmentally friendly alternative to the highly toxic element mercury.

Beginning in the 1960s, gallium’s application in semiconductor production caused a shift in commercial use, and today 98% of available gallium is consumed by the semiconductor industry.

Compounds

95% of gallium consumed worldwide is in the form of the compound gallium arsenide. The next most common is gallium nitride, formed when gallium reacts with ammonia.

Sources

Gallium does not occur as a free element in nature but as trace amounts of gallium(III) compounds in zinc ores, such as sphalerite, and in the aluminum ore bauxite. It is extracted as a byproduct of smelting these ores.  

Fun Facts

It's magic!

Gallium’s melting point is so low you can melt it in the palm of your hand! Magicians sometimes use spoons made of gallium to perform magic tricks—they use the heat from their fingers to melt the metal, appearing to bend the spoon with their minds.

Range is everything

Gallium has a huge liquid range. It has one of the widest ranges of temperatures over which it remains liquid (neptunium has the widest). The difference between gallium’s melting point and boiling point is over 2300°C!

The gallium anomaly

The gallium anomaly refers to experiments using gallium to detect solar neutrinos, but scientists found way fewer neutrinos than they expected. Where did all the neutrinos go?! Scientists figured out that neutrinos can change into different types (electron, muon, and tau), and the gallium detectors could only capture electron neutrinos. They couldn’t detect any other forms! Gallium played a key role in identifying this neutrino behavior and advancing our understanding of particle physics.

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