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Gadolinium

64
157.3
Gd
Gadolinium

Element Stats

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Physical

Physical Properties
PropertyValuePropertyValue
AppearanceSoft, silvery-white metal
ClassificationLanthanidesDensity7.899 g/cm³ at STP
Boiling Point3546 KMelting Point1585 K

Atomic

Atomic Properties
PropertyValuePropertyValue
Atomic Number64Atomic Mass157.253
Van Der Waals Radius237Atomic Radius (empirical)180

Electronic & Chemical

Electronic and Chemical Properties
PropertyValuePropertyValue
Electronegativity1.2Electron Affinity13.22 kJ/mol
Electron Configuration1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f7 5d1
Oxidation States1, 2, 3
Ionization Energies

Showing all 4 ionization energies.

  1. 593.4 kJ/mol
  2. 1170 kJ/mol
  3. 1990 kJ/mol
  4. 4250 kJ/mol

History

Gadolinium was officially discovered in 1880, but it might have been found sooner! The element takes its name from gadolinite, a mineral that was in turn named after Johan Gadolin, a Finnish chemist and mineralogist. Gadolinite was named after Gadolin in recognition of the fact that he discovered the element yttrium from a sample of gadolinite in 1792. But Gadolin missed the other nine new elements that were also inside the mineral!

Element 64 was one of those hidden elements, but in fairness it's only present in gadolinite in very small amounts. Gadolinium was ultimately found in the mineral by Swiss chemist Jean Charles Galissard de Marignac in a sample almost 90 years later. De Marignac named the element after the gadolinite and, by extension, after Gadolin. Although Gadolin didn't discover element 64, he still ended up having the element named after him!

Properties

Gadolinium is a silvery white metal. It is malleable, which means that it can be easily shaped, and ductile, meaning that it can stretch without breaking. In moist air, gadolinium tarnishes quickly. The element is also highly magnetic.

Uses

Mixing gadolinium into metals like iron or chromium can make those metals easier to work with. Because gadolinium is great at absorbing neutrons, it’s often used in nuclear reactors. Gadolinium is also used in magnetic resonance imaging (MRI). By injecting a gadolinium mixture into a patient’s bloodstream, doctors can more easily see inside a patient’s body. About one third of MRIs involve the use of gadolinium!

Gadolinium is also useful for making magnets and electronics like compact discs. Gadolinium yttrium aluminum garnets are a type of crystal that’s often used in lasers.

Compounds

Gadolinium forms most of its compounds in its +3 oxidation state (meaning it loses three of its electrons). Many of these compounds are useful in MRI imaging.

In the past, other gadolinium compounds were used in television tubes. However, this use has declined because new televisions don’t use tubes. 

Forms

In nature, gadolinium is found in six stable (non-radioactive) isotopes—gadolinium-154, gadolinium-155, gadolinium-156, gadolinium-157, gadolinium-158, and gadolinium-160, along with one unstable, or radioactive isotope, gadolinium-152. About a quarter of naturally occurring gadolinium is in the form of gadolinium-160.

Altogether, 33 radioactive gadolinium isotopes have been observed. The most stable—naturally-occurring gadolinium-152—has a half-life of 1.08×1014 years. Most of the other isotopes have half-lives of less than 25 seconds.

Sources

Gadolinium is a rare-earth element that’s found alongside many other rare-earth elements, such as monzanite and bastnäsite. Although the element is technically named after the mineral gadolinite, gadolinium is only a trace element in that mineral.

Most commercially produced gadolinium comes from China, the United States, Brazil, Sri Lanka, India, and Australia.

Fun Facts

Turning up the heat

Gadolinium is magnetocaloric, meaning it warms up if you put it in a magnetic field. You can feel this if you ever have an MRI with gadolinium contrast. When you go in the MRI machine, the magnetic field acts on the injected gadolinium, making you feel all warm and tingly.

Neutron poison

Gadolinium is so good at absorbing neutrons that it’s called a neutron or nuclear poison. Nuclear reactions happen when neutrons hit a nucleus that splits apart, releasing more neutrons and causing a chain reaction. Gadolinium acts like a sponge, absorbing neutrons to slow down and control nuclear reactions. The element is crucial to the safety and stability of nuclear reactors.

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