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Americium

95
243
Am
Americium

Element Stats

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Physical

Physical Properties
PropertyValuePropertyValue
Appearancesilvery white
ClassificationActinidesDensity12 g/cm³ at STP
Boiling Point2880 KMelting Point1449 K

Atomic

Atomic Properties
PropertyValuePropertyValue
Atomic Number95Atomic Mass243
Van Der Waals Radius244Atomic Radius (empirical)173

Electronic & Chemical

Electronic and Chemical Properties
PropertyValuePropertyValue
Electronegativity1.13Electron Affinity9.93 kJ/mol
Electron Configuration1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s2 5f7
Oxidation States8, 7, 6, 5, 4, 3, 2
Ionization Energies

Showing all 1 ionization energies.

  1. 578 kJ/mol

History

Americium was first intentionally produced and identified in late 1944 at the University of California, Berkeley as part of the Manhattan Project by Glenn Seaborg, Ralph James, Leon Morgan, and Albert Ghiorso. It was chemically identified at the Metallurgical Laboratory of the University of Chicago. Although it is the third element in the transuranic series, it was the fourth transuranic element to be discovered. Its discovery was kept secret and wasn't released to the public until November 1945.

Americium is a man-made radioactive chemical element. It is a transuranic (meaning beyond uranium) member of the actinide series. In the periodic table, it is located under its twin lanthanide element, europium. Matching its twin, it was named americium by analogy and because it was first produced in the United States.

Properties

Americium is a highly radioactive, silvery-white, man-made element. It slowly tarnishes in dry air at room temperature. Americium is less dense than both curium and plutonium; but has a higher density than europium—mostly because of its higher atomic mass. Americium is relatively soft and easily deformable. It readily reacts with oxygen and dissolves in aqueous acids. Its melting point is 1176°C, its boiling point is 2011°C, and its density is 12 g/cm3.

Uses

Americium can be produced in kilogram quantities and has few practical uses. Americium is commonly used in smoke alarms, keeping us firesafe.

Americium is used in smoke detectors for its alpha particles. Alpha particles ionize air molecules creating negatively and positively charged particles. There is a constant flow of the charged particles inside the smoke detector, and when broken by smoke, the alarm is triggered.

Americium can also be used as a portable source of gamma rays for medical and industrial uses, such as spectroscopy, radiography, and the creation of flat glass. It has the potential to be used in spacecraft batteries in the future, but that use is hindered by the scarcity and high price of this element ($1500/gram).

Compounds

Americium reacts with oxygen to form the dioxide AmO2. It reacts with halogen elements to form compounds such as tetrafluoride (AmF4). It reacts with hydrogen to form the hydride AmH2. It has four oxidation states in acidic aqueous solutions: Am3+ (pink), Am4+ (rose colored and very unstable), AmO2+ (yellow), and AmO22+ (light tan).

Forms

There are at least 19 radioactive isotopes. The longest-lived and most common isotopes of americium, americium-241 and -243, have half-lives of 432.2 and 7,370 years, respectively. Because of the length of these half-lives, any americium that was present during the formation of the earth should have decayed by now. Americium-241 produces about three times as much alpha radiation as radium.

Sources

Americium is produced by bombarding uranium or plutonium with neutrons in nuclear reactors. It also is concentrated in areas that were used for atmospheric nuclear tests and nuclear accident sites, such as Chernobyl.

Americium has also been theoretically detected in stars. It may occur naturally in extremely small trace amounts in uranium minerals because of nuclear reactions.

Fun Facts

Powering spacecraft

Atomic space batteries work by releasing heat as the radioactive materials inside them decay. This heat helps prevent spacecraft from freezing and can be converted into electricity to power the craft. Americium is being explored as a new powersource for these batteries. Plutonium is currently used, but americium has a much longer half-life and is better suited for long missions.

A Nuclear Reactor and a Boy Called Lovey

In the Big Bang Theory spin-off Young Sheldon, the child prodigy attempts to build a nuclear reactor by collecting americium from almost 60 broken smoke detectors. His attempts are thwarted by the authorities, but it wouldn’t have worked anyway. We did the math: it would take at least 3 billion smoke detectors to get enough americium to make a small nuclear reactor.

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